Vertical Alignment of Liquid Crystals on Comb-Like Renewable Chavicol-Modified Polystyrene

Dopant-Enhanced Vertical Alignment of Negative Liquid Crystals

A simple method for achieving high-contrast vertical alignment of high birefringence (Dn 0.28) negative dielectric anisotropic liquid crystal mixture using buffed polyimide substrates is demonstrated. By doping a positive, or non-polar dielectric anisotropic compound or mixture to the laterally difluorinated tolane liquid crystal host, an excellent vertical alignment was obtained. This alignmen...

Zeolite-like liquid crystals

Zeolites represent inorganic solid-state materials with porous structures of fascinating complexity. Recently, significant progress was made by reticular synthesis of related organic solid-state materials, such as metal-organic or covalent organic frameworks. Herein we go a step further and report the first example of a fluid honeycomb mimicking a zeolitic framework. In this unique self-assembl...

Substrate-induced bulk alignment of liquid crystals.

Photo-Induced Vertical Alignment of Liquid Crystals via In Situ Polymerization Initiated by Polyimide Containing Benzophenone

Vertical alignment of liquid crystal (LC) was achieved in an easy and effective way: in situ photopolymerization of dodecyl acrylate (DA) monomers initiated by polyimide based on 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and 3,3′-dimethyl-4,4′-diaminodiphenyl methane (BTDA-DMMDA PI). The alignment behavior and alignment stabilities were characterized by a polarizing optical microscope (...

Self-alignment of liquid crystals in three-dimensional photonic crystals.

We report on the observation of self-alignment of nematic liquid crystals into colloidal photonic crystals, over distances much larger than the typical size of the voids between the spheres. We observe that the infiltrated structure possesses a unique optical axis that is determined by an intrinsic structural anisotropy of photonic crystal opals. We develop a simple model to describe this self-...